If one drive is NVMe, and the other SATA, then I believe the boot loader location selector will work. The installer default for installing grub now is the ESP of an NVMe drive if there is one, but I do recall choosing the ESP on the SATA drive (which is sda1) as my choice and it was used for this installation. See below: root partition is on a logical volume on the NVMe, and ESP on sda1. (I could have installed root on sda as well, as the OP plans to do, but lose the speedy access.)
Code:
dmn@Sydney:~$ space
Filesystem Size Used Avail Use% Mounted on
udev 5.8G 0 5.8G 0% /dev
tmpfs 1.2G 1.9M 1.2G 1% /run
/dev/mapper/sn500_vg-ubuntu_1804 26G 23G 2.1G 92% /
tmpfs 5.8G 0 5.8G 0% /dev/shm
tmpfs 5.0M 4.0K 5.0M 1% /run/lock
tmpfs 5.8G 0 5.8G 0% /sys/fs/cgroup
/dev/mapper/os_vg2-Common 85G 48G 33G 60% /mnt/Common-Files
/dev/mapper/sn500_vg-vm_disks 183G 107G 68G 62% /mnt/VM-Disks2
/dev/sda1 79M 25M 55M 31% /boot/efi
tmpfs 1.2G 24K 1.2G 1% /run/user/1000
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