What specifically are you asking help for? Does Ubuntu load correctly? Do you get the Grub boot menu which allows you to select either Ubuntu or Windows 10? If, so, does Windows 10 load correctly?
There really is not much difference between installing the Nvidia drivers by ticking Install Third Party Software during installation and using Software & Updates>Additional Drivers tab to install the Nvidia drivers after installation. In both cases we get the proprietary video driver.
The failure to correctly detect both monitors has nothing to do with secure boot stuff. That information is a distraction. It might have something to do with the video driver. We can disable the proprietary video driver through Software & Updates>Additional Drivers tab. With a reboot we will load Ubuntu using an open source video driver.
Actually there is an important difference. Ticking Install third part software also installs some non-free video and audio codecs that are very useful. We can install these afterwards also.
It might help if you told us the model of the Nvidia video card that is in that machine. Some of us here might have knowledge of issues with Nvidia drivers for that model when using Ubuntu 21.04.
Regards
P.S. According to this post what you experienced regarding secure boot; passwords & MOK management is standard procedure.
https://gist.github.com/bitsurgeon/b...8fe8bbc346c029
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