NFS is trivial to configure - one line in one file - vs Samba that has a 3 inch thick book. So the choice is obvious.
Apart from NFS, you can also use FTP, WebDAV, SSH, Netcat - a veritable zoo of ad hoc network methods. Usually, I don't bother with NFS even. I just run sshd on each machine, put the host names in the hosts file and copy files around with scp, either from the command line, or with Konqueror or Dolphin.
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