Try this one:
Using a command name by itself assumes that the application is installed in /usr/bin, which isn't always the case. "./" in a Terminal indicates the current directory.
If the application can't be executed from its own directory via ./<appname>, then something more serious is at play here.
If this IS the problem, then - assuming the application is completely standalone - you can remedy it by doing this (hold Alt and hit F2 for a Run prompt):
Code:
gksudo nautilus /home& gksudo nautilus /usr/bin/&
Then, just open your home directory in the /home window, track down the proper executable, and drag-and-drop it to the /usr/bin window.
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