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I have face the same problem after installing XAMPP. But when I sign out from skype, it was running absolutely.

Actually Apache server use port 80 and if your computer connected with skype then...

Or, Just select start button and select search from start menu. From the left side of the window make sure to look in Local drive C:\ or the drive name where you install xampp. Then in the blank...

You can try this path in your address bar: C:\xampp\htdocs. It will be redirected you to htdocs. file.

Do you install WordPress in your Xampp server?