+1 on the Gparted Livecd.
Remember, every time you install a distro it will install it's own bootloader. Most distros are pretty good at picking up already installed os's but sometimes they don't. If that happens don't panic because it is easy to fix with a little editing.
AND, if you later decide to reinstall Windows it will re-write the mbr wiping out any other bootloader. Once again an easy fix.
Multi-disk multi-booting is easy. Here is an excerpt from my setup (edited for space)...
Code:
Disk /dev/sda: 320.0 GB, 320072933376 bytes
Device Boot Start End Blocks Id System
/dev/sda1 63 620526689 310263313+ 5 Extended
/dev/sda5 126 12546764 6273319+ 82 Linux swap / Solaris
/dev/sda6 12546828 53817749 20635461 83 Linux
/dev/sda7 53817813 136086614 41134401 83 Linux
/dev/sda8 136086678 301764959 82839141 83 Linux
/dev/sda9 * 301765023 461145824 79690401 83 Linux
/dev/sda10 461145888 615112784 76983448+ 83 Linux
Disk /dev/sdb: 80.0 GB, 80026361856 bytes
Device Boot Start End Blocks Id System
/dev/sdb1 * 63 156296384 78148161 7 HPFS/NTFS
Disk /dev/sdc: 160.0 GB, 160041885696 bytes
Device Boot Start End Blocks Id System
/dev/sdc1 * 63 146914424 73457181 83 Linux
/dev/sdc2 146914425 312576704 82831140 5 Extended
/dev/sdc5 146914488 312576704 82831108+ 83 Linux
sda=SATA
sdb=PATA
sdc=PATA
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