run gstreamer-properties (for Totem Movie Player) or go into the vlc video output preferences, and change the video output method to X11 (it might be listed as "no xv" in gstreamer preferences) - it'll use a little more processing power (translated: your battery will die faster if you're playing videos away from an outlet), but it should fix any problems with compiz messing up your video output - your video should continue playing even if you activate scale or the cube.
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