Did you switch to Analog Surround 5.1 Ouput (Volume Control > Configuration)?
Furthermore, you could try to increase the Master and/or PCM volume directly using alsamixer:
Well, the most annoying thing, the crackling noise, has been caused by the proprietary ATI/AMD fglrx driver. I had to disable hardware acceleration (display compositing, xrender) to get clean sound.
Code:
Multimedia audio controller: Creative Labs SB Live! EMU10k1 (rev 0a)
Subsystem: Creative Labs SB Live! 5.1 Digital OEM [SB0220]
Flags: bus master, medium devsel, latency 32, IRQ 16
I/O ports at dc00 [size=32]
Capabilities: <access denied>
Kernel driver in use: snd_emu10k1
Kernel modules: snd-emu10k1
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