Is this an older BIOS that only supports IDE drives? You may then only be able to boot primary master drive.
Older computers let you choose floppy or hard drive and hard drive had to be jumpered to be primary master. They then added CDs and other devices and most newer computers that support SATA drives also let you choose which hard drive is the boot drive in BIOS rather than with jumpers (or cable select) on hard drive.
If you can only boot primary master and can boot windows then you do not have grub installed to the primary master. If you have newer BIOS you should be able to change drive boot order to drive with grub installed.
If you have server install, it is not liveCD. Download liveCD and run this:
Boot Info Script courtesy of forum member meierfra
Page with instructions and download:
http://bootinfoscript.sourceforge.net/
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