If you can't do it through the Administration->Users panel, then here's how you could do this manually. You might make another admin user, log into that, and then change your real account from there.
let's say your account is "rocky" and you want to change it to "bullwinkle".
Code:
sudo mv /home/rocky /home/bullwinkle
sudo usermod -l bullwinkle rocky
sudo usermod -d /home/bullwinkle bullwinkle
sudo groupmod -n bullwinkle rocky
1. we rename the home directory.
2. usermod -l changes the login name for user 'rocky' to 'bullwinkle'
3. usermod -d sets the directory for user bullwinkle to "/home/bullwinkle"
4. groupmod -n changes the name of bullwinkle's user group to be bullwinkle too.
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